@article {2148,
	title = {ORGANOMETALLIC THIAZENES - OXIDATIVE ADDITION OF S4N4 TO LOW-VALENT METALS - ELECTROCHEMISTRY AND N-15 NMR OF CPCOS2N2 AND CP-ASTERISK-COS2N2},
	journal = {Journal of Organometallic Chemistry},
	volume = {467},
	number = {1},
	year = {1994},
	note = {Times Cited: 11Boere, rt klassen, b moock, kh},
	month = {Mar},
	pages = {127-133},
	abstract = {The reactions of S4N4 with CpM(CO)x and Cp*M(CO)x (M = Mn, Fe, Co, Ni and Rh) result in tractable products only when M = Co. The electrochemical behaviour of the previously known complexes CPCoS2N2 and Cp*CoS2N2 has been investigated by DC and AC cyclic voltammetry. Each has a single one-electron reduction process occurring at -0.65 V (Cp) and -0.99 V (Cp*). vs. SCE, in CH2Cl2 solution. For the Cp complex, chemical reduction using cobaltocene has also been achieved. 15N NMR spectra were recorded for 99\% N-15 enriched samples: 550 (broad singlet) and 431 (singlet) for Cp, 518 (broad singlet) and 404 ppm (singlet) for Cp*, referenced to liquid NH3. The electronic absorption spectra are also reported, and interpreted in the light of EHMO calculations.},
	isbn = {0022-328X},
	url = {<Go to ISI>://WOS:A1994MY33300017},
	author = {Boer{\'e}, R. T. and Klassen, B. and Moock, K. H.}
}
