@article { ISI:000395753300012,
	title = {{{The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*(2)(RN=)(2)S]},
	journal = {CHEMISTRY-A EUROPEAN JOURNAL},
	volume = {23},
	number = {6},
	year = {2017},
	month = {JAN},
	pages = {1278-1290},
	abstract = {The first lanthanide complexes with a redox-active sulfur diimide ligand, [LnCp*(2)(Me3SiN=)(2)S] (Ln= Sm, Eu, Yb; Cp*=eta(5)-C5Me5), are reported. The complexes were synthesized by using [LnCp*(2)(THF)(2)] and (Me3SiN=)(2)S and have been thoroughly characterized by single-crystal X-ray diffraction, EPR spectroscopy, UV/Vis/NIR electronic absorption spectroscopy and SQUID magnetometry. The results, as in-terpreted by CASSCF/SOC-RASSI calculations providing a non-perturbative treatment of spin-orbit coupling, indicate that these paramagnetic complexes are best described as Ln3+ and [( Me3SiN=)(2)S]-(center dot) adducts. As such, these complexes contain the first isolated and structurally characterized acyclic [(RN=)(2)S](-center dot) radical anions.},
	issn = {0947-6539},
	doi = {10.1002/chem.201604340},
	author = {Klementyeva, Svetlana V. and Gritsan, Nina P. and Khusniyarov, Marat M. and Witt, Alexander and Dmitriev, Alexey A. and Suturina, Elizaveta A. and Hill, Nathan D. D. and Roemmele, Tracey L. and Gamer, Michael T. and Boer{\'e}, R. T. and Roesky, Peter W. and Zibarev, Andrey V. and Konchenko, Sergey N.}
}
