Citation:
Roemmele TL, Boeré RT. 4-Methyl-N '-(2,2,2-trichloroethanimidoyl)benzene-1-carboximidamide. Acta Crystallographica Section E-Structure Reports Online [Internet]. 2011;67:O3137-U2086.
Abstract:
The title compound, C(10)H(10)Cl(3)N(3), features a delocalized unsaturated N - C - N - C - N chain and strong intramolecular N-H center dot center dot center dot N hydrogen bonding across the chelate ring and also intramolecular N-H center dot center dot center dot Cl contacts to a CCl(3)-group Cl atom. The only intermolecular contacts in the lattice are non-classical hydrogen bonds between methyl and CCl(3) groups. The pseudo-six-membered ring is distinctly non-planar by virtue of rotation about the N-C bond between the carboximidamide and imine components [C-N-C-N torsion angle = -23.6 (2)degrees].
Notes:
Times Cited: 0Roemmele, Tracey L. Boere, Rene T.Part 12