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THE ELECTROCHEMISTRY AND ELECTRONIC-STRUCTURE OF HIGH-VALENT MOLYBDENUM AND TUNGSTEN METALLACYCLES

Citation:

Boeré RT, Klassen V, Moock KH. THE ELECTROCHEMISTRY AND ELECTRONIC-STRUCTURE OF HIGH-VALENT MOLYBDENUM AND TUNGSTEN METALLACYCLES. Phosphorus Sulfur and Silicon and the Related Elements [Internet]. 1994;93:249-252.

Abstract:

The metallacycles [NPPh(2)NPPh(2)NMCl(3)], M=Mo, W have been studied in CH2Cl2 using cyclic voltammetry. The observed redox potentials indicate that the cyclic pi-base ligand, [NPPh(2)NPPh(2)N](3-), is capable of stabilising high oxidation states in both molybdenum and tungsten complexes. Empirical MO calculations are presented which rationalize the electronic structure of the metallacycles.

Notes:

Times Cited: 2Boere, rt klassen, v moock, kh7th International Symposium on Inorganic Ring Systems (IRIS VII)Aug 07-12, 1994Banff, canadaAlberta sulphur res ltd, canadian soc chem, inorgan chem div, univ calgary, dept chem, elf atochem, elsevier sci, univ calgary, fac sci, gordon & breach publ inc, john wiley & sons ltd, monsanto, nat sci & engn res council, canada, univ calgary, res grants comm, vch publ

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