eta(1) and eta(2) complexes of lambda(3)-1,2,4,6-thiatriazinyls with CpCr(CO)(x)

Citation:

Ang CY, Boeré RT, Goh LY, Koh LL, Kuan SL, Tan GK, Yu X. eta(1) and eta(2) complexes of lambda(3)-1,2,4,6-thiatriazinyls with CpCr(CO)(x). Chemical Communications [Internet]. 2006:4735-4737.

Abstract:

The title heterocyclic radicals coordinate to either 17e CpCr(CO)(3) or 15e CpCr(CO)(2) moieties as one-electron or as three-electron donors, respectively; in the former the bonding is via the perpendicular p orbital of the sulfur atom, while in the latter bonding is via p(pi) orbitals on both sulfur and nitrogen.

Notes:

Times Cited: 7Ang, Chwee Ying Boere, Rene T. Goh, Lai Yoong Koh, Lip Lin Kuan, Seah Ling Tan, Geok Kheng Yu, Xin

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