Citation:
Boeré RT, Cole ML, Junk PC, Masuda JD, Wolmershauser G. An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated "phosphaamidinate" anion. Chemical Communications [Internet]. 2004:2564-2565.
Abstract:
The reaction of DippPH(2) ( Dipp = 2,6-(Pr2C6H3)-Pr-i) with DippN=C(p-CH3C6H4)Cl in refluxing xylenes affords DippP=C(p-CH3C6H4)N(H) Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.
Notes:
Times Cited: 14Boere, RT Cole, ML Junk, PC Masuda, JD Wolmershauser, G