Citation:
Oshovsky GV, Ouali A, Xia N, Zablocka M, Boeré RT, Duhayon C, Taillefer M, Majoral JP. Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media. Organometallics [Internet]. 2008;27:5733-5736.
Abstract:
A straightforward and efficient synthetic route to thiazolyl phosphines is reported. Moreover, the first application of these molecules in catalysis is described. These phosphines are excellent ligands in the copper-catalyzed arylation and vinylation of nucleophiles. The reactions could be performed in acetonitrile and various mixed aqueous/organic solvents and even in pure water in the presence of a phase transfer catalyst. In each case, coupling products are obtained with high yields at very mild temperatures.
Notes:
Times Cited: 11Oshovsky, Gennady V. Ouali, Armelle Xia, Ning Zablocka, Maria Boere, Rene T. Duhayon, Carine Taillefer, Marc Majoral, Jean Pierre