CHEM 2600 Exercises

06 Addition Reactions to Polar Pi Bonds (Carbonyls, Nitriles, etc.)

The exercise are not listed in numerical order because it makes more sense to group the electrophilic additions together and to group the nucleophilic additions together.  Since I cannot edit these documents, I cannot renumber them.

Exercise 100: Electrophilic Additions to Carbonyls23 KB
Exercise 100: Electrophilic Additions to Carbonyls (Answers)35 KB
Exercise 101: Hemiacetals and Acetals24 KB
Exercise 101: Hemiacetals and Acetals (Answers)33 KB
Exercise 102: Acetals as Protecting Groups26 KB
Exercise 102: Acetals as Protecting Groups (Answers)31 KB
Exercise 94: Nucleophilic Addition vs. Electrophilic Addition32 KB
Exercise 94: Nucleophilic Addition vs. Electrophilic Addition (Answers)42 KB
Exercise 95: Acetylide Anions29 KB
Exercise 95: Acetylide Anions (Answers)36 KB
Exercise 96: Making Grignard and Alkyllithium Reagents24 KB
Exercise 96: Making Grignard and Alkyllithium Reagents (Answers)27 KB
Exercise 97: Reactions of Grignard and Alkyllithium Reagents25 KB
Exercise 97: Reactions of Grignard and Alkyllithium Reagents (Answers)31 KB
Exercise 98: Incompatibilities31 KB
Exercise 98: Incompatibilities (Answers)34 KB
Exercise 99: Nucleophilic Addition of Hydride to Carbonyls32 KB
Exercise 99: Nucleophilic Addition of Hydride to Carbonyls (Answers)38 KB
Exercise 103: Nucleophilic Addition of Nitrogen to Carbonyls39 KB
Exercise 103: Nucleophilic Addition of Nitrogen to Carbonyls (Answers)59 KB
Exercise 104: Applications26 KB
Exercise 104: Applications (Answers)40 KB